From 216 outcomes to unequal totals
Six possible values on each of three dice produce 216 ordered outcomes. A particular sequence, such as 1 on the first die, 2 on the second and 3 on the third, is one outcome with a 1/216 probability for fair independent dice.
Total six is not limited to that sequence. Other values and orders also produce six. To calculate the probability of a total, count every relevant combination; totals from 3 to 18 cannot be divided into equal probability shares.
Why to check triples first
Under conventional small/big rules, the triple exception is an additional condition beyond the total range. Declaring 'small' as soon as you see a total of six omits the important distinction in 2,2,2.
Small, big, a specific total and a particular face are separate conditions. One condition's exception cannot automatically be applied to every other condition. Check the version-specific payouts and provisions separately rather than treating a general example as a full schedule.